I used to trap the skunks off my line before fox seasons started so the skunks wouldn't spoil my fox sets. A 22 Short in the lungs and come backs later to pick them up. This is no BS for some reason if you talk quietly to them they seem so settle/relax before you shoot. It works for a live trap too so you can drape a tarp over the trap and haul it away without spraying. I would tan some of them and make mittens.
Short story: I was working for the WI Youth Conservation Corps. In the 1960s and during a evening BS session I convinced a city kid that if you can catch a skunk and quickly pull its tail between its legs it won't spray. Needless to say he got sprayed big time before he ever caught the skunk. They made me share a room with him, that room might still stink. When I was a kid I got sprayed in the face by a skunk, I don't really smell skunk as bad as others, I don't find road killed skunks really too offensive.