Hotter may not be better...in some ML applications it has even been proven to be counter productive.
Case in point is using 209 shotshell primers....some have noted that the charge actually gets moved down the barrel a little way before igniting. Not good in those cases.
Some aftermarket concepts for using primers in some sort of sleeve, be it a .25 cal case trimmed in length or other steel sleeves are recommending the use of small pistol or rifle primers.
Example is this ad from Cabela's:
VariFlame™ Primer Adapter
Every muzzleloader shooter knows the importance of finding just the right combination of propellant, projectile and ignition to achieve maximum efficiency and accuracy from their firearm. The Vari-Flame Adapter adds the option of using small pistol or small rifle centerfire primers in place of a standard 209 shotshell primer. In some firearms the use of these primers can result in significantly reduced fouling and greater accuracy. The VariFlame Adapter looks like a 209 shotshell primer with a receiver area machined out to accept centerfire primers, and fits in the 209 breech plug receiver of all muzzleloaders that accept 209 ignition. The kit includes 10 all-brass, reusable VariFlame Adapters, a depriming base and a capping/decapping tool with handle. Use small rifle or small pistol primers only. Primers sold separately. Replacement Primer Adapters are available Per 10.