Quote:Is this a sign of excessive headspace?
It can be.
The shiny ring can be a warning of impending case head separation which can be caused by pushing the soulder too far back during the resizing operation. The case wall stretches on firing to fill the chamber and since case head cannot stretch, stretching occurs where the case wall joins the case head & brass becomes thinner at that point resulting in the visible ring.
Straighten a paper clip, then bend a 90* hook on the end and use as a "feeler" inside the cases. If you can feel a groove, case could be close to separting.
Regards,
hm